Diastereoselective synthesis of meso-pillar[6]arenes by bridging between hydroquinone units in an alternating up-and-down manner.
نویسندگان
چکیده
We report the first synthesis of bridged pillararenes. Meso-form pillar[6]arenes were diastereo-selectively formed by bridging units of a per-hydroxylated pillar[6]arene in an alternating up-and-down manner with dialkyldichlorosilanes.
منابع مشابه
The template effect of solvents on high yield synthesis, co-cyclization of pillar[6]arenes and interconversion between pillar[5]- and pillar[6]arenes.
We have synthesized a pillar[6]arene in high yield and a co-pillar[6]arene using chlorocyclohexane as a solvent.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 38 شماره
صفحات -
تاریخ انتشار 2013